GENERATION OF THE PF2((A)OVER-TILDE(4)A(2)) RADICAL AND ASSIGNMENT OF THE PF2((A)OVER-TILDE-(X)OVER-TILDE) EMISSION-SPECTRUM

被引：16

作者：

ZHAO, Y

SETSER, DW

机构：

[1] Department of Chemistry, Kansas State University, Manhattan

来源：

CHEMICAL PHYSICS LETTERS | 1993年 / 210卷 / 4-6期

关键词：

D O I：

10.1016/0009-2614(93)87037-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The PF2(a 4A2) radical has been generated by flowing PF3 through a dc discharge using He or Ar carrier ps. The PF2(a 4A2-X B-2(1)) low-resolution emission spectrum has been analyzed to obtain upsilon0, omega1', omega2' and some anharmonic constants. The radiative lifetime of the PF2(a 4A2) state is greater-than-or-equal-to 1.9 ms.

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页码：362 / 366

页数：5

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