ALKYLIDENATION OF KETONES BY GEM-DIBROMOALKANE, SMI2, AND SM IN THE PRESENCE OF CATALYTIC AMOUNT OF CRCL3

被引：26

作者：

MATSUBARA, S ^{[1
]}

HORIUCHI, M ^{[1
]}

TAKAI, K ^{[1
]}

UTIMOTO, K ^{[1
]}

机构：

[1] OKAYAMA UNIV, FAC ENGN, DEPT APPL CHEM, OKAYAMA 700, JAPAN

来源：

CHEMISTRY LETTERS | 1995年 / 04期

关键词：

D O I：

10.1246/cl.1995.259

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Alkylidenation of ketones can be performed by the reaction with geminal dibromoalkane-SmI2-Sm in the presence of catalytic amount of CrCl3 at room temperature yielding the alkylidenated products in good to excellent yields.

引用

页码：259 / 260

页数：2

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