DIVALENT LANTHANIDES IN ORGANIC-CHEMISTRY

被引：23

作者：

KAGAN, HB

COLLIN, J

NAMY, JL

BIED, C

DALLEMER, F

LEBRUN, A

机构：

[1] Laboratoire de Synthese Asymetrique (Unite de Recherche associee au CNRS 1497), Institut de Chimie Moléculaire d'Orsay, Université Paris-Sud

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 1993年 / 192卷 / 1-2期

关键词：

D O I：

10.1016/0925-8388(93)90228-F

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

SmX2 (X = halide) and SmCp2 were used comparatively to promote various organic transformations. SmCp2 leads to isolable organosamarium complexes, which are able to react with electrophiles. The mechanism of the samarium Barbier reaction is discussed in the light of new experiments.

引用

页码：191 / 196

页数：6

共 37 条

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