SYNTHESIS AND REACTIVITY OF BENZYLIC AND ALLYLIC SAMARIUM COMPOUNDS

被引：30

作者：

BIED, C ^{[1
]}

COLLIN, J ^{[1
]}

KAGAN, HB ^{[1
]}

机构：

[1] UNIV PARIS 11,INST CHIM MOLEC ORSAY,CNRS,SYNTH ASYMETR LAB,F-91405 ORSAY,FRANCE

来源：

TETRAHEDRON | 1992年 / 48卷 / 19期

关键词：

DICYCLOPENTADIENYL SAMARIUM; BENZYL SAMARIUM COMPLEXES; ALLYL SAMARIUM COMPLEXES; KETONES; ACID CHLORIDES;

D O I：

10.1016/S0040-4020(01)88468-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Benzyl and allyl samarium species are prepared by reaction of benzylic or allylic chlorides with SmCp2. They present a wide scope of reactivity towards aldehydes, ketones and acid chlorides.

引用

页码：3877 / 3890

页数：14

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