PEROXY-RADICALS IN THE ROSE EXPERIMENT - MEASUREMENT AND THEORY

被引:85
作者
CANTRELL, CA
LIND, JA
SHETTER, RE
CALVERT, JG
GOLDAN, PD
KUSTER, W
FEHSENFELD, FC
MONTZKA, SA
PARRISH, DD
WILLIAMS, EJ
BUHR, MP
WESTBERG, HH
ALLWINE, G
MARTIN, R
机构
[1] NOAA, AERONOMY LAB, BOULDER, CO 80303 USA
[2] CHEM ENGN LAB ATMOSPHER RES, PULLMAN, WA USA
关键词
D O I
10.1029/92JD01727
中图分类号
P4 [大气科学(气象学)];
学科分类号
0706 ; 070601 ;
摘要
The concentrations of the HO2-RO2 species measured during July 11, 1990. in the ROSE (Rural Oxidants in the Southern Environment) study m Alabama are compared to those expected in theory from calculations based upon detailed hourly measurements of a variety of trace gases including the hydrocarbons, NO. NO2, carbonyl -pounds. CO, PAN (peroxyacetylnitrate) and calculated j(O3) values. The measurements are also compared with the [HO2] + [RO2] as estimated from deviations from the NO2+ hv (+02) reversible NO + 03 photostationary state. Within the error of the measurements all of the data appear to be in reasonable accord.
引用
收藏
页码:20671 / 20686
页数:16
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