SYNTHESIS AND PROPERTIES OF AROMATIC TELECHELIC MONODISPERSE DIOLS .1. RADICAL-INITIATED ADDITION OF 10-UNDECEN-1-OL TO NEW AROMATIC ALPHA,OMEGA-DITHIOLS

被引：9

作者：

AMEDURI, B ^{[1
]}

BOUTEVIN, B ^{[1
]}

KHAMLICHI, M ^{[1
]}

ROBIN, JJ ^{[1
]}

ELIDRISSI, A ^{[1
]}

RAMDANI, A ^{[1
]}

机构：

[1] UNIV OUJDA,DEPT CHEM,OUJDA,MOROCCO

来源：

MACROMOLECULAR CHEMISTRY AND PHYSICS | 1994年 / 195卷 / 10期

关键词：

D O I：

10.1002/macp.1994.021951012

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The synthesis of aromatic telechelic monodisperse diols produced from the radical-initiated addition reation of a two-fold excess of 10-undecen-1-ol and new alpha,omega-dithiols is presented. The dithiols were prepared by esterification of thioglycolic acid with monodisperse telechelic diols obtained by fractionation of oligo(ethylene terephthalate)s and oligo(tetramethylene terephthalate)s. In all the cases, the long-chain alpha,omega-diols were produced selectively and quantitatively. The diols are soluble in most organic solvents, contrary to classical oligo(ethylene terephthalate)s and oligo(tetramethylene terephthalate)s.

引用

页码：3425 / 3443

页数：19

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