(4S,8S)-4,8-BIS(DIPHENYLMETHYL)-1,5,7-TRIAZABICYCLO[4,4,0]DEC-5-ENE - A HINDERED, CHIRAL, BICYCLIC GUANIDINE BASE WITH EFFECTIVE C-2-SYMMETRY

被引：14

作者：

BOYLE, PH ^{[1
]}

DAVIS, AP ^{[1
]}

DEMPSEY, KJ ^{[1
]}

HOSKEN, GD ^{[1
]}

机构：

[1] UNIV DUBLIN TRINITY COLL,DEPT CHEM,DUBLIN 2,IRELAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 16期

关键词：

D O I：

10.1039/c39940001875

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound 5 is prepared from L-methionine and investigated by computational, NMR spectroscopic and other techniques; the results indicate that the N/NH groups of 5 and its conjugate acid occupy hindered, chiral environments due to the disposition of the bulky diphenylmethyl substituents.

引用

页码：1875 / 1876

页数：2

共 19 条

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