PALLADIUM-CATALYZED COUPLING OF ALLYLIC CYCLIC CARBONATES WITH IODOBENZENE AND HYPERVALENT IODONIUM SALTS

被引：51

作者：

KANG, SK

JUNG, KY

PARK, CH

JANG, SB

机构：

[1] Department of Chemistry, Sung Kyun Kwan University, Suwon, 440-746, Natural Science Campus

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 44期

关键词：

D O I：

10.1016/0040-4039(95)01704-L

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Palladium-catalyzed arylation of allylic cyclic carbonates with iodobenzene in the presence of Pd(OAc)(2) as catalyst afforded the phenyl-substituted allylic alcohols via palladium oxygen beta-elimination, However, palladium-catalyzed arylation, alkenylation, and alkynylation of allylic cyclic carbonates with iodonium tetrafluoroborates afforded the phenyl, alkenyl, and alkynyl-substituted allylic cyclic carbonates without reductive ring opening under aqueous and nonaqueous conditions.

引用

页码：8047 / 8050

页数：4

共 15 条

[1]

Heck R.F., 1985, PALLADIUM REAGENTS O

[2]

HECK RF, 1982, ORG REACTIONS, V27, P345

[3] PALLADIUM-CATALYZED REACTIONS OF ORGANIC HALIDES WITH OLEFINS [J].