HIGH-PRECISION ASYMMETRIC-SYNTHESIS OF STEGOBIOL AND STEGOBINONE VIA BORONIC ESTERS

被引：35

作者：

MATTESON, DS

MAN, HW

机构：

[1] Department of Chemistry, Washington State University, Pullman

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1993年 / 58卷 / 24期

关键词：

D O I：

10.1021/jo00076a006

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Highly stereoselective boronic ester chemistry has been used to synthesize the drugstore beetle pheromones stegobiol and stegobinone. The convergent route utilizes a single intermediate containing all of the stereogenic centers for both segments of the pheromones, requires only one chromatographic separation, and is the first synthesis to provide pure, crystalline samples.

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页码：6545 / 6547

页数：3

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