HIGH-PRECISION ASYMMETRIC-SYNTHESIS OF STEGOBIOL AND STEGOBINONE VIA BORONIC ESTERS

被引：35

作者：

MATTESON, DS

MAN, HW

机构：

[1] Department of Chemistry, Washington State University, Pullman

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1993年 / 58卷 / 24期

关键词：

D O I：

10.1021/jo00076a006

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Highly stereoselective boronic ester chemistry has been used to synthesize the drugstore beetle pheromones stegobiol and stegobinone. The convergent route utilizes a single intermediate containing all of the stereogenic centers for both segments of the pheromones, requires only one chromatographic separation, and is the first synthesis to provide pure, crystalline samples.

引用

页码：6545 / 6547

页数：3