ENZYME-CATALYZED CONDENSATION POLYMERIZATION OF 11-HYDROXYUNDECANOIC ACID WITH LIPASE FROM CANDIDA-CYLINDRACEA

被引:38
作者
OHAGAN, D
ZAIDI, NA
机构
[1] Department of Chemistry, Science Laboratories, University of Durham, Durham, DH1 3LE, South Road
关键词
CONDENSATION POLYMERIZATION; LIPASE; 11-HYDROXYUNDECANOIC ACID;
D O I
10.1016/0032-3861(94)90928-8
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The enzyme-catalysed condensation polymerization of 11-hydroxyundecanoic acid in hexane with the lipase from Candida cylindracea is reported. Molecular weights up to 35000 are attained. A time course study of the polymerization process reveals that oligomers are formed relatively rapidly and that these oligomers then condense to generate higher molecular weight polyesters.
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页码:3576 / 3578
页数:3
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