POLYMERIZATION OF 10-HYDROXYDECANOIC ACID WITH THE LIPASE FROM CANDIDA-CYLINDRACEA

被引:27
作者
OHAGAN, D
ZAIDI, NA
机构
[1] Department of Chemistry, University of Durham, Science Laboratories, Durham DH1 3LE, South Road
来源
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1993年 / 20期
关键词
D O I
10.1039/p19930002389
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A polyester of 10-hydroxydecanoic acid 1 has been efficiently prepared by the incubation of the monomer in hexane and 3 angstrom molecular sieves at 55-degrees-C with the lipase from Candida cylindracea. The polymer is on average a 52mer(M(n)BAR = 9346 and M(r) = 12 065) and has a polydispersity of 1.29.
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页码:2389 / 2390
页数:2
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