SYNTHESIS OF A C-14,C-15 DIHYDRO DERIVATIVE OF THE SOUTH HEXACYCLIC STEROID UNIT OF CEPHALOSTATIN-1 .2. SPIROKETAL SYNTHESIS AND STEREOCHEMICAL ASSIGNMENT BY NMR-SPECTROSCOPY

被引：17

作者：

BHANDARU, S ^{[1
]}

FUCHS, PL ^{[1
]}

机构：

[1] PURDUE UNIV, DEPT CHEM, W LAFAYETTE, IN 47907 USA

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 46期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/0040-4039(95)01805-R

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Transformation of aldehyde 3 into 2, a C-14',C-15' dihydro analog of the ''South'' hexacyclic spiroketal of cephalostatin 11 is described. The stereochemistry of 2 was elucidated by NMR spectroscopy.

引用

页码：8351 / 8354

页数：4

共 10 条

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[7] ANTINEOPLASTIC AGENTS .214. ISOLATION AND STRUCTURE OF CEPHALOSTATINS 7-9
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[8] ISOLATION AND STRUCTURE OF CEPHALOSTATIN-10 AND CEPHALOSTATIN-11
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[9] THE USE OF CHLOROACETIC ACID IN THE MITSUNOBU REACTION
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