A HIGHLY SYMMETRICAL SIXFOLD CYCLOADDITION PRODUCT OF FULLERENE C-60

被引：93

作者：

KRAUTLER, B

MAYNOLLO, J

机构：

[1] Institut für Organische Chemie, Universität Innsbruck, A-6020

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1995年 / 34卷 / 01期

关键词：

DIELS-ALDER REACTIONS; FULLERENES;

D O I：

10.1002/anie.199500871

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In one step and with 26% yield, a sixfold Diels‐Alder product is formed from buckminsterfullerene C60 and 2,3‐dimethyl‐1,3‐butadiene. This first direct synthesis of a highly symmetric, exohedrally sixfold substituted fullerene addition product is remarkably simple. The components were heated in ortho‐dichlorobenzene at roughly 110°C for ten days, and the product was purified by column chromatography. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：87 / 88

页数：2

共 55 条

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