REAGENT CONTROL IN THE ALDOL ADDITION-REACTION OF CHIRAL BORON ENOLATES WITH CHIRAL ALDEHYDES

被引：14

作者：

GENNARI, C

MORESCA, D

VULPETTI, A

PAIN, G

机构：

[1] Dip. di Chimica Organica e Industriale, Universita' di Milano, Centro CNR (Sost.Org.Nat.), 20133 Milano

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 26期

关键词：

D O I：

10.1016/S0040-4039(00)60746-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Boron enolates bearing menthone-derived chiral ligands are capable of fair to excellent diastereocontrol in their reactions with chiral aldehydes. Thioester-derived (better than ketone derived) enolates are able to control aldol stereochemistry irrespective of the aldehyde preferences.

引用

页码：4623 / 4626

页数：4

共 16 条

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