SYNTHESIS AND TRANSFORMATIONS OF METALLOCYCLES .14. STEREOSELECTIVE SYNTHESIS OF TRANS-3,4-DIALKYLTETRAHYDROTHIOPHENES

被引：12

作者：

DZHEMILEV, UM

IBRAGIMOV, AG

AZHGALIEV, MN

MUSLUKHOV, RR

机构：

[1] Ural Branch of the Russian Academy of Sciences, Institute of Organic Chemistry, Ufa, 450054

来源：

RUSSIAN CHEMICAL BULLETIN | 1994年 / 43卷 / 02期

关键词：

TRANS-3,4-DISUBSTITUTED TETRAHYDROTHIOPHENES; SYNTHESIS;

D O I：

10.1007/BF00695822

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A one-pot stereoselective method was developed for the synthesis of trans-3,4-dialkyltetrahydrothiophenes from alpha-olefins, EtAlCl(2), metallic magnesium, and elementary sulfur (S-8) in the presence of catalytic amounts of Cp(2)ZrCl(2).

引用

页码：255 / 257

页数：3

共 12 条

[1] NONTRADITIONAL APPROACH TO THE SYNTHESIS OF 3-SUBSTITUTED TETRAHYDROTHIOPHENES AND TETRAHYDROSELENOPHENES
DZHEMILEV, UM
IBRAGIMOV, AG
ZOLOTAREV, AP
TOLSTIKOV, GA
[J]. BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1989, 38 (06): : 1324 - 1324
[2] SYNTHESIS AND TRANSFORMATIONS OF METALLOCYCLES .13. STEREOSELECTIVE TRANSFORMATION OF TRANS-3,4-DIALKYLALUMACYCLOPENTANES TO TRANS-3,4-DIALKYLCYCLOBUTANES
DZHEMILEV, UM
IBRAGIMOV, AG
AZHGALIEV, MN
ZOLOTAREV, AP
MUSLUKHOV, RR
[J]. RUSSIAN CHEMICAL BULLETIN, 1994, 43 (02) : 252 - 254
[3] SYNTHESIS AND CONVERSIONS OF METALLOCYCLES .7. A NOVEL-APPROACH TO THE SYNTHESIS OF 3,4-DIALKYL-SUBSTITUTED ALUMINACYCLOPENTANES IN THE PRESENCE OF CP2ZRCL2
DZHEMILEV, UM
IBRAGIMOV, AG
MOROZOV, AB
MUSLUKHOV, RR
TOLSTIKOV, GA
[J]. BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1991, 40 (07): : 1425 - 1427
[4] 1ST PREPARATIVE SYNTHESIS OF ALUMOCYCLOPENTANES INVOLVING ZIRCONIUM COMPLEXES
DZHEMILEV, UM
IBRAGIMOV, AG
ZOLOTAREV, AP
MUSLUKHOV, RR
TOLSTIKOV, GA
[J]. BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1989, 38 (01): : 194 - 195
[5] A NEW METHOD FOR THE SYNTHESIS OF MONOALKYL-SUBSTITUTED CYCLOBUTANES
DZHEMILEV, UM
IBRAGIMOV, AG
ZOLOTAREV, AP
MUSLUKHOV, RR
TOLSTIKOV, GA
[J]. BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1989, 38 (09): : 1981 - 1981
[6] A NEW METHOD FOR THE SYNTHESIS OF 1,1-DISUBSTITUTED CYCLOPROPANES
DZHEMILEV, UM
IBRAGIMOV, AG
ZOLOTAREV, AP
MUSLUKHOV, RR
TOLSTIKOV, GA
[J]. BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1990, 39 (05): : 1071 - 1071
[7] DZHEMILEV UM, 1990, B ACAD SCI USSR CH, V39, P21
[8] ELIEL EL, 1978, TOP STEREOCHEM, V10, P349
[9] FILIPPOVA TM, 1971, KHIM GETEROTSIKL+, P316
[10] IONIN BI, 1983, YAMR SPEKTROSKOPIYA

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