A SYNTHESIS OF THE TETRAENE FRAGMENT OF CALYCULINS AS ITS ANTIPODAL FORM

被引：23

作者：

MATSUBARA, J ^{[1
]}

NAKAO, K ^{[1
]}

HAMADA, Y ^{[1
]}

SHIOIRI, T ^{[1
]}

机构：

[1] NAGOYA CITY UNIV,FAC PHARMACEUT SCI,MIZUHO KU,NAGOYA,AICHI 467,JAPAN

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 29期

关键词：

D O I：

10.1016/S0040-4039(00)74685-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The antipodal form 2 of the tetraene fragment, the C1- C12 portion, of calyculins (1) has been synthesized by use of the stereoselective hydrogenation of the butenolide 6 followed by the successive Wittig-type chain elongation of the lactol 9 as key steps.

引用

页码：4187 / 4190

页数：4

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