FACILE ABSTRACTION OF CHEMISORBED-D ON SI(100) BY ATOMIC-H

被引:72
作者
KOLESKE, DD [1 ]
GATES, SM [1 ]
SCHULTZ, JA [1 ]
机构
[1] IONWERKS INC,HOUSTON,TX 77005
关键词
D O I
10.1063/1.465955
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The abstraction of chemisorbed deuterium (D) on Si(100) by atomic hydrogen (H(at)) is studied in real time. The surface H and D coverages are measured by mass analyzing the recoiled H+ and D+ ion signals during the abstraction reaction. We find that H(at) efficiently removes adsorbed D on Si(100) with a low activation energy of 0.8+/-0.6 kcal/mol and a reaction probability that is 0.36 times the H(at) adsorption rate on clean Si(100).
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页码:5619 / 5622
页数:4
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