STRUCTURAL CHARACTERIZATION OF CLUSTERS OF PERYLENE WITH ARGON AND NEON BY ROTATIONAL COHERENCE SPECTROSCOPY

被引：28

作者：

OHLINE, SM

JOIREMAN, PW

CONNELL, LL

FELKER, PM

机构：

[1] Department of Chemistry and Biochemistry, University of California, Los Angeles

来源：

CHEMICAL PHYSICS LETTERS | 1992年 / 191卷 / 3-4期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0009-2614(92)85315-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Rotational coherence spectroscopy has been used to measure rotational constants of the perprotonated and perdeuterated isotopomers of perylene-Ar, two isomers of perylene-(Ar)2, perylene-Ne, and perylene-(Ne)2. A structural analysis of the various species has been performed based on these results. A comparison of the geometries so obtained with those proposed by others based on potential energy calculations and vibronic frequency shifts confirms the validity of the latter approach for perylene(rare gas)n species.

引用

收藏

页码：362 / 370

页数：9

相关论文

共 41 条

[31] ADSORPTION OF RARE-GAS ATOMS ON MICROSURFACES OF LARGE AROMATIC-MOLECULES [J].

LEUTWYLER, S ;

JORTNER, J .

JOURNAL OF PHYSICAL CHEMISTRY, 1987, 91 (22) :5558-5568

[32] THE STRUCTURE OF FLUORENE (C13H10) AND THE FLUORENE ARGON VANDERWAALS COMPLEX FROM A HIGH-RESOLUTION NEAR ULTRAVIOLET-SPECTRUM [J].

MEERTS, WL ;

MAJEWSKI, WA ;

VANHERPEN, WM .

CANADIAN JOURNAL OF PHYSICS, 1984, 62 (12) :1293-1299

[33] MODEL-CALCULATIONS OF POTENTIAL SURFACES OF VAN DER WAALS COMPLEXES CONTAINING LARGE AROMATIC-MOLECULES [J].

ONDRECHEN, MJ ;

BERKOVITCHYELLIN, Z ;

JORTNER, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (22) :6586-6592

[34] THE 2ND CONFORMER OF THE BENZENE ARGON2 VANDERWAALS COMPLEX [J].

SCHMIDT, M ;

MONS, M ;

LECALVE, J ;

MILLIE, P ;

COSSARTMAGOS, C .

CHEMICAL PHYSICS LETTERS, 1991, 183 (1-2) :69-76

[35] SPECTROSCOPY OF PERYLENE ALKANE VANDERWAALS COMPLEXES [J].

SCHWARTZ, SA ;

TOPP, MR .

JOURNAL OF PHYSICAL CHEMISTRY, 1984, 88 (23) :5673-5678

[36] PICOSECOND FLUORESCENCE DEPLETION SPECTROSCOPY .3. INTRAMOLECULAR VIBRATIONAL-RELAXATION IN THE EXCITED ELECTRONIC STATE OF PARA-CYCLOHEXYLANILINE [J].

SMITH, PG ;

MCDONALD, JD .

JOURNAL OF CHEMICAL PHYSICS, 1990, 92 (02) :1004-1014

[37] PICOSECOND FLUORESCENCE DEPLETION SPECTROSCOPY TO MEASURE ROTATIONAL-CONSTANTS IN THE EXCITED ELECTRONIC STATE OF P-CYCLOHEXYLANILINE [J].

SMITH, PG ;

MCDONALD, JD .

JOURNAL OF CHEMICAL PHYSICS, 1990, 92 (06) :3991-3992

[38] ROTATIONALLY RESOLVED SPECTROSCOPY OF DEUTERATED FLUORENE AND THE FLUORENE-ARGON VANDERWAALS COMPLEX [J].

VANHERPEN, WM ;

MEERTS, WL .

CHEMICAL PHYSICS LETTERS, 1988, 147 (01) :7-12

[39] STRUCTURE OF THE BENZENE-AR2 CLUSTER FROM ROTATIONALLY RESOLVED ULTRAVIOLET SPECTROSCOPY [J].

WEBER, T ;

NEUSSER, HJ .

JOURNAL OF CHEMICAL PHYSICS, 1991, 94 (12) :7689-7699

[40] VANDERWAALS BOND LENGTHS AND ELECTRONIC SPECTRAL SHIFTS OF THE BENZENE-KR AND BENZENE-XE COMPLEXES [J].

WEBER, T ;

RIEDLE, E ;

NEUSSER, HJ ;

SCHLAG, EW .

CHEMICAL PHYSICS LETTERS, 1991, 183 (1-2) :77-83

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