INTRAMOLECULAR BASE STABILIZATION OF COBALT-GALLIUM AND COBALT-INDIUM COMPOUNDS

被引：36

作者：

OLAZABAL, CA

GABBAI, FP

COWLEY, AH

CARRANO, CJ

MOKRY, LM

BOND, MR

机构：

[1] UNIV TEXAS,DEPT CHEM & BIOCHEM,AUSTIN,TX 78712

[2] SW TEXAS STATE UNIV,DEPT CHEM,SAN MARCOS,TX 78666

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 02期

关键词：

D O I：

10.1021/om00014a008

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The intermetallic derivatives [{(2,6-Me2-NCH2)2C6H3}M{Co(CO)4}2] (M = Ga (1); M = In (2)) have been prepared. X-ray analysis reveals that only one of the dimethylamine groups is coordinated to Ga in 1 and as a consequence the CGaCo2 moiety is pyramidal; the indium analogue 2 possesses a distorted-trigonal-bipyramidal geometry and a planar CInCo2 unit.

引用

页码：421 / 423

页数：3

共 17 条

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