SYNTHESES OF THE FUNGICIDE/INSECTICIDE ALLOSAMIDIN AND A STRUCTURAL ISOMER

被引:39
作者
BLATTNER, R
FURNEAUX, RH
KEMMITT, T
TYLER, PC
FERRIER, RJ
TIDEN, AK
机构
[1] VICTORIA UNIV WELLINGTON,DEPT CHEM,WELLINGTON,NEW ZEALAND
[2] IND RES LTD,LOWER HUTT,NEW ZEALAND
来源
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1994年 / 23期
关键词
D O I
10.1039/p19940003411
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A synthesis of the naturally occurring inhibitor of chitin metabolism, allosamidin 1, involves, as the key step condensation between the allosaminozoline derivative 39, prepared following oxyamination of the cyclopentene 19, and the disaccharide glycosylating agent 54 which was synthesised from 2-acetamido-2-deoxy-D-glucose. The structural isomer 59 of allosamidin is also reported. Brief biological test results obtained using isomers 1 and 59 are recorded.
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页码:3411 / 3421
页数:11
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