THE BONDING CAPABILITY OF IMIDO COMPLEX FRAGMENTS OF GROUPS-5-7 WITH REGARD TO THE ISOLOBAL RELATIONSHIP

被引：50

作者：

SUNDERMEYER, J

RUNGE, D

机构：

[1] Institut Für Anorganische Chemie, Universität Würzburg, D-97074, Am Hubland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 12期

关键词：

D O I：

10.1002/anie.199412551

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The same number of valence orbitals and valence electrons, as well as valence orbitals of similar symmetry and energy, results when the cyclopentadienyl ligand in [(η5‐C5R′5)M] is substituted by an imido ligand NR and the metal atom by an isoelectronic M′ of the next higher group (see the series below). Through coupling of the imido complex fragments with [CpFe(CO)2], the characteristic bonding capability of each entity can be determined. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

收藏

页码：1255 / 1257

页数：3

相关论文

共 44 条

[21]

JORGENSEN KA, 1993, INORG CHEM, V32, P1521

[22] STRUCTURE AND CHEMISTRY OF BIS(CYCLOPENTADIENYL)-MLN COMPLEXES [J].

LAUHER, JW ;

HOFFMANN, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (07) :1729-1742

[23] SYNTHESIS AND REACTIVITY OF SILICON TRANSITION-METAL COMPLEXES .5. MODIFIED ALKALI SALT ELIMINATION METHOD - GENERAL PROCEDURE FOR SYNTHESIS OF SILICON TRANSITION-METAL COMPOUNDS [J].

MALISCH, W ;

KUHN, M .

CHEMISCHE BERICHTE-RECUEIL, 1974, 107 (03) :979-995

[24] KINETIC AND THERMODYNAMIC ACIDITY OF HYDRIDO TRANSITION-METAL COMPLEXES .3. THERMODYNAMIC ACIDITY OF COMMON MONONUCLEAR CARBONYL HYDRIDES [J].

MOORE, EJ ;

SULLIVAN, JM ;

NORTON, JR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (09) :2257-2263

[25] ELECTROPHILIC VS NUCLEOPHILIC REACTIVITY IN COMPLEXES CONTAINING MULTIPLY-BONDED (ALKYLIDENE, IMIDO OR OXO) LIGANDS - A CONCEPTUAL-MODEL [J].

NUGENT, WA ;

MCKINNEY, RJ ;

KASOWSKI, RV ;

VANCATLEDGE, FA .

INORGANICA CHIMICA ACTA-LETTERS, 1982, 65 (03) :L91-L93

[26]

NUGENT WA, 1988, METAL LIGAND MULTIPL

[27] OXO-HYDRIDO AND IMIDO-HYDRIDO DERIVATIVES OF PERMETHYLTANTALOCENE - STRUCTURES OF (ETA 5C5ME5)2TA(=O)H AND (ETA-5C5ME5)2TA(=NC6H5)H - DOUBLY OR TRIPLY BONDED TANTALUM OXO AND IMIDO LIGANDS [J].

PARKIN, G ;

VANASSELT, A ;

LEAHY, DJ ;

WHINNERY, L ;

HUA, NG ;

QUAN, RW ;

HENLING, LM ;

SCHAEFER, WP ;

SANTARSIERO, BD ;

BERCAW, JE .

INORGANIC CHEMISTRY, 1992, 31 (01) :82-85

[28] HALF-SANDWICH NIOBIUM(III) NITRENE (IMIDO) COMPLEXES CONTAINING CARBONYL, ALKENE AND ACETYLENE LIGANDS [J].

POOLE, AD ;

GIBSON, VC ;

CLEGG, W .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (03) :237-239

[29] ORGANOMETALLIC IMIDO COMPLEXES HIGHERVALENT DERIVATIVES OF THE D-METAL ADIDS .2. ALKYLPENTADIENYL, ARYLPENTADIENYL, AND CYCLOPENTADIENYL-SUBSTITUTED MOLYBDENUM(VI) AND TUNGSTEN(VI) IMIDO COMPLEXES [J].

RADIUS, U ;

SUNDERMEYER, J .

CHEMISCHE BERICHTE-RECUEIL, 1992, 125 (10) :2183-2186

[30] SYNTHESIS AND STRUCTURE OF [(NME2)3TIFE(CO)2(CP)] A STABLE IRON-TITANIUM BOND [J].

SARTAIN, WJ ;

SELEGUE, JP .

ORGANOMETALLICS, 1987, 6 (08) :1812-1815

← 1 2 3 4 5 →