PHOTOINDUCED ELECTRON-TRANSFER, GEMINATE RECOMBINATION, AND DIFFUSION IN LIQUID SOLUTION

被引：27

作者：

DORFMAN, RC ^{[1
]}

LIN, Y ^{[1
]}

FAYER, MD ^{[1
]}

机构：

[1] STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1990年 / 94卷 / 21期

关键词：

D O I：

10.1021/j100384a003

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A theory of photoinduced electron transfer with geminate recombination that includes the effects of spatial diffusion of the donor and the acceptor molecules in liquid solution is developed. The theory is an extension of the recent exact treatment of this problem in solid solution in which the particle positions are fixed. Example calculations are presented that illustrate the electron-transfer dynamics. The method is valid for any diffusion constant and any set of electron-transfer parameters. © 1990 American Chemical Society.

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页码：8007 / 8009

页数：3

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