The synthesis of solid ingots of high-purity GaP by reacting phosphine with molten Ga at 1000 to 1200 C is described. Actual growth parameters were measured during synthesis and compared with the values predicted from solution growth theory. Growth rates of about 1. 7/10//5 cm/sec were possible with this system for a solution saturated with P at 12pp C. Some properties of the synthesized material are presented.
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Bass S. J., 1968, Journal of Crystal Growth, V3-4Spe, P286, DOI 10.1016/0022-0248(68)90155-3