SOLID-STATE MAGNETIC-RESONANCE STUDY OF NAC60(THF)(3)

被引：6

作者：

CHEN, J

CAI, RF

HUANG, ZE

SHAO, QF

CHEN, SM

机构：

[1] FUDAN UNIV,DEPT CHEM,SHANGHAI 200433,PEOPLES R CHINA

[2] FUDAN UNIV,ANAL & MEASUREMENT RES CTR,SHANGHAI 200433,PEOPLES R CHINA

来源：

SOLID STATE COMMUNICATIONS | 1995年 / 95卷 / 04期

关键词：

FULLERENES; CHEMICAL SYNTHESIS; ELECTRON PARAMAGNETIC RESONANCE; NUCLEAR RESONANCES;

D O I：

10.1016/0038-1098(95)00204-9

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

NaC60(TBF)(3) has been prepared via a new solution-phase route. The solid-state variable temperature ESR and C-13 NMR studies on NaC60(THF)(3) (in comparison with NaC60(THF)(5)) suggest that the unusual down-field chemical shift in C-60(-) (relative to C-60) can be understood partially on the basis of Pasquarello et al's model.

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收藏

页码：239 / 243

页数：5

相关论文

共 12 条

[1] A NEW METHOD FOR THE PREPARATION OF FULLERENE ANION SALTS - SYNTHESIS AND CHARACTERIZATION OF KC60(THF) [J].

CHEN, J ;

HUANG, ZE ;

CAI, RF ;

SHAO, QF ;

CHEN, SM ;

YE, HJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (18) :2177-2178

[2] STUDIES ON RARE-EARTH INDENYL COMPOUNDS .2. SYNTHESIS AND CRYSTAL-STRUCTURE OF HEXAKIS(TETRAHYDROFURAN)SODIUM (MU-CHLORO)BIS(TRIINDENYLNEODYMATE) [J].

CHEN, MQ ;

WU, WL ;

ZHUANG, SM ;

HUANG, ZE .

ORGANOMETALLICS, 1988, 7 (04) :802-806

[3] SYNTHESIS AND CHARACTERIZATION OF NAC60-CENTER-DOT-5THF [J].

DOUTHWAITE, RE ;

BROUGH, AR ;

GREEN, WLH .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (03) :267-268

[4] ELECTROREDUCTION OF BUCKMINSTERFULLERENE, C-60, IN APROTIC-SOLVENTS - ELECTRON-SPIN-RESONANCE CHARACTERIZATION OF SINGLY, DOUBLY, AND TRIPLY REDUCED C-60 IN FROZEN-SOLUTIONS [J].

DUBOIS, D ;

JONES, MT ;

KADISH, KM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (16) :6446-6451

[5] SUPERCONDUCTIVITY AT 18-K IN POTASSIUM-DOPED C-60 [J].

HEBARD, AF ;

ROSSEINSKY, MJ ;

HADDON, RC ;

MURPHY, DW ;

GLARUM, SH ;

PALSTRA, TTM ;

RAMIREZ, AP ;

KORTAN, AR .

NATURE, 1991, 350 (6319) :600-601

[6] NEW METALLIC C-60 COMPOUND - NAXC60(THF)(Y) [J].

KOBAYASHI, H ;

TOMITA, H ;

MORIYAMA, H ;

KOBAYASHI, A ;

WATANABE, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (07) :3153-3154

[7] ABINITIO MO STUDY OF THE C-60 ANION RADICAL - THE JAHN-TELLER DISTORTION AND ELECTRONIC-STRUCTURE [J].

KOGA, N ;

MOROKUMA, K .

CHEMICAL PHYSICS LETTERS, 1992, 196 (1-2) :191-196

[8] RING CURRENTS IN TOPOLOGICALLY COMPLEX-MOLECULES - APPLICATION TO C60, C70, AND THEIR HEXA-ANIONS [J].

PASQUARELLO, A ;

SCHLUTER, M ;

HADDON, RC .

PHYSICAL REVIEW A, 1993, 47 (03) :1783-1789

[9] CHARGED-PHONON ABSORPTION IN DOPED C-60 [J].

RICE, MJ ;

CHOI, HY .

PHYSICAL REVIEW B, 1992, 45 (17) :10173-10176

[10]

SCRIVENS WA, 1993, J AM CHEM SOC, V114, P7917