RHODIUM-MEDIATED 100-PERCENT REGIOSELECTIVE OXIDATIVE HYDROAMINATION OF ALPHA-OLEFINS

被引:52
作者
BRUNET, JJ [1 ]
NEIBECKER, D [1 ]
PHILIPPOT, K [1 ]
机构
[1] INST NATL POLYTECH TOULOUSE,F-31077 TOULOUSE,FRANCE
关键词
D O I
10.1016/S0040-4039(00)79252-5
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The system generated from lithium anilide and [(Et3P)2RhCl]2 catalyzes (turnover 21) the regioselective condensation of aniline with styrene to give a mixture of PhNH-CH(CH3)Ph (hydroamination product) and PhN=C(CH3)Ph (oxidative hydroamination product) in c.a.1/2 ratio. This 100% regioselective oxidative hydroamination has been confirmed in the case of 1-hexene.
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页码:3877 / 3880
页数:4
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