CYCLOADDITION OF NITRILE OXIDES TO HOMOCHIRAL VINYL ETHERS

被引：25

作者：

BOA, AN ^{[1
]}

DAWKINS, DA ^{[1
]}

HERGUETA, AR ^{[1
]}

JENKINS, PR ^{[1
]}

机构：

[1] UNIV LEICESTER,DEPT CHEM,LEICESTER LE1 7RH,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1994年 / 08期

关键词：

D O I：

10.1039/p19940000953

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In the [3 + 2] cycloaddition of a range of nitrile oxides with homochiral vinyl ethers the diastereoselectivity observed is dependent on the chiral auxiliary used. A brief comparison is made with the diastereoselectivity of the corresponding [4 + 2] nitrosoalkene cycloaddition, and also to the nitrile oxide cycloaddition to chiral acrylic acid esters bearing the most successful auxiliaries from the vinyl ether study.

引用

页码：953 / 960

页数：8

共 39 条

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