THE ISOINVERSION PRINCIPLE FOR THE ASYMMETRIC TAUTOMERIZATION OF PHOTODIENOLS

被引：33

作者：

MUZART, J

HENIN, F

PETE, JP

MBOUNGOUMPASSI, A

机构：

[1] Unité Réarrangements Thermiques et Photochimiques Associée au C.N.R.S., Université de Reims Champagne-Ardenne

来源：

TETRAHEDRON-ASYMMETRY | 1993年 / 4卷 / 12期

关键词：

D O I：

10.1016/S0957-4166(00)82233-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

From the study of the tautomerization of prochiral dienols photogenerated in an organic solvent between -76 and +30 degrees C in the presence of optically active aminoalcohols and in using the methodology developed by Scharf's group, the isoinversion temperature of the asymmetric process has been estimated to be -55 degrees C.

引用

页码：2531 / 2534

页数：4

共 31 条

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