AN UNEXPECTED REVERSAL OF STEREOCHEMISTRY IN A MODIFICATION OF THE RYCHNOVSKY CYANOHYDRIN ALKYLATION

被引：8

作者：

BRZEZINSKI, LJ ^{[1
]}

LEVY, DD ^{[1
]}

LEAHY, JW ^{[1
]}

机构：

[1] UNIV CALIF BERKELEY,DEPT CHEM,BERKELEY,CA 94720

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 41期

关键词：

D O I：

10.1016/S0040-4039(00)78353-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alkylation of cyanohydrin 1,3-acetonides with unsaturated substitution at the 2-position is described. The stereochemistry of the products obtained from this reaction was opposite to that anticipated.

引用

页码：7601 / 7604

页数：4

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