Enhancement of CO2/CH4 selectivity in metal-organic frameworks containing lithium cations

被引：118

作者：

Bae, Youn-Sang ^{[1
]}

Hauser, Brad G. ^{[2
,3
]}

Farha, Omar K. ^{[2
,3
]}

Hupp, Joseph T. ^{[2
,3
]}

Snurr, Randall Q. ^{[1
]}

机构：

[1] Northwestern Univ, Dept Chem & Biol Engn, Evanston, IL 60208 USA

[2] Northwestern Univ, Int Inst Nanotechnol, Evanston, IL 60208 USA

[3] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

来源：

MICROPOROUS AND MESOPOROUS MATERIALS | 2011年 / 141卷 / 1-3期

关键词：

Lithium doping; Carbon dioxide (CO2); Metal-organic framework (MOF); Separation; Adsorption; ZEOLITIC IMIDAZOLATE FRAMEWORKS; HYDROGEN STORAGE; CARBON-DIOXIDE; SURFACE-AREA; ADSORPTION; SEPARATION; GAS; CO2; COORDINATION; H-2;

D O I：

10.1016/j.micromeso.2010.10.048

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Incorporation of Li cations into MOFs by either of two methods, chemical reduction or cation exchange, significantly improves the CO2/CH4 selectivity. While the selectivity enhancement by the chemical reduction seems to come from favorable displacement of catenated frameworks, the selectivity improvement by the Li cation exchange comes from enhanced solid-gas interactions. (C) 2010 Elsevier Inc. All rights reserved.

引用

页码：231 / 235

页数：5

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