Modulation of the photophysical properties of BODIPY dyes by substitution at their meso position.

被引：66

作者：

Banuelos, Jorge ^{[1
]}

Arroyo-Cordoba, Ismael J. ^{[2
]}

Valois-Escamilla, Ismael ^{[3
]}

Alvarez-Hernandez, Alejandro ^{[3
]}

Pena-Cabrera, Eduardo ^{[2
]}

Hu, Rongrong ^{[4
]}

Tang, Ben Zhong ^{[4
]}

Esnal, Ixone ^{[1
]}

Martinez, Virginia ^{[1
]}

Lopez Arbeloa, Inigo ^{[1
]}

机构：

[1] Univ Basque Country, Dept Quim Fis, EHU, E-48080 Bilbao, Spain

[2] Univ Guanajuato, Dept Quim, Guanajuato 36050, Gto, Mexico

[3] Univ Autonoma Estado Hidalgo, Ctr Invest Quim, Mineral De La Reforma 42076, Hidalgo, Mexico

[4] Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China

来源：

RSC ADVANCES | 2011年 / 1卷 / 04期

关键词：

INTRAMOLECULAR CHARGE-TRANSFER; ENERGY-TRANSFER; ELECTRON-TRANSFER; BORON-DIPYRRIN; STRUCTURAL CONTROL; LASING PROPERTIES; FLUORESCENT DYES; LASER PROPERTIES; ACCEPTOR; PHOTOSTABILITY;

D O I：

10.1039/c1ra00020a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report the photophysical properties of new BODIPY derivatives monosubstituted at the central position. The presence of different functional groups induced the appearance of new photophysical processes in BODIPY dyes, such as intramolecular charge or energy transfer. These phenomena are sensitive to solvent properties (mainly the polarity) and have a potential use as fluorescent probes. Adequate modifications in their molecular structure or in the environment polarity can modulate the emission region of these fluorophores in the visible spectral region. Specifically, different processes and photophysical behaviors can be achieved depending on the excited chromophore and/or the solvent characteristics in a bichromophoric pyrene-BODIPY system.

引用

页码：677 / 684

页数：8

共 70 条

[31] A near-IR emitting Bodipy-based dye fitted with ancillary light harvesting units [J].

Harriman, Anthony ;

Mallon, Laura J. ;

Goeb, Sebastien ;

Ziessel, Raymond .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2007, 9 (38) :5199-5201

[32] Electronic Energy Transfer to the S2 Level of the Acceptor in Functionalised Boron Dipyrromethene Dyes [J].

Harriman, Anthony ;

Mallon, Laura J. ;

Goeb, Sebastien ;

Ulrich, Gilles ;

Ziessel, Raymond .

CHEMISTRY-A EUROPEAN JOURNAL, 2009, 15 (18) :4553-4564

[33]

HAUGLAND RP, 1999, HDB FLUORESCENT PROV

[34] Twisted Intramolecular Charge Transfer and Aggregation-Induced Emission of BODIPY Derivatives [J].

Hu, Rongrong ;

Lager, Erik ;

Aguilar-Aguilar, Angelica ;

Liu, Jianzhao ;

Lam, Jacky W. Y. ;

Sung, Herman H. Y. ;

Williams, Ian D. ;

Zhong, Yongchun ;

Wong, Kam Sing ;

Pena-Cabrera, Eduardo ;

Tang, Ben Zhong .

JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (36) :15845-15853

[35] Synthesis of new, BODIPY-based sensors and labels [J].

Kalai, Tamas ;

Hideg, Kalman .

TETRAHEDRON, 2006, 62 (44) :10352-10360

[36] Structural control of the photodynamics of boron-dipyrrin complexes [J].

Kee, HL ;

Kirmaier, C ;

Yu, LH ;

Thamyongkit, P ;

Youngblood, WJ ;

Calder, ME ;

Ramos, L ;

Noll, BC ;

Bocian, DF ;

Scheidt, WR ;

Birge, RR ;

Lindsey, JS ;

Holten, D .

JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (43) :20433-20443

[37] Correlations of structure and rates of energy transfer for through-bond energy-transfer cassettes [J].

Kim, TG ;

Castro, JC ;

Loudet, A ;

Jiao, JGS ;

Hochstrasser, RM ;

Burgess, K ;

Topp, MR .

JOURNAL OF PHYSICAL CHEMISTRY A, 2006, 110 (01) :20-27

[38] Solid-State Dye-Sensitized Solar Cells Using Red and Near-IR Absorbing Bodipy Sensitizers [J].

Kolemen, Safacan ;

Cakmak, Yusuf ;

Erten-Ela, Sule ;

Altay, Yigit ;

Brendel, Johannes ;

Thelakkat, Mukundan ;

Akkaya, Engin U. .

ORGANIC LETTERS, 2010, 12 (17) :3812-3815

[39] Novel meso-Polyarylamine-BODIPY Hybrids: Synthesis and Study of Their Optical Properties [J].

Lager, Erik ;

Liu, Jianzhao ;

Aguilar-Aguilar, Angelica ;

Tang, Ben Zhong ;

Pena-Cabrera, Eduardo .

JOURNAL OF ORGANIC CHEMISTRY, 2009, 74 (05) :2053-2058

[40] Electrogenerated chemiluminescence 71.: Photophysical, electrochemical, and electrogenerated chemiluminescent properties of selected dipyrromethene-BF2 dyes [J].

Lai, RY ;

Bard, AJ .

JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (21) :5036-5042

← 1 2 3 4 5 6 7 →