石墨烯/高分子复合薄膜的制备及应用

被引:23
作者
于小雯
石高全
机构
[1] 清华大学化学系
关键词
石墨烯; 氧化石墨烯; 高分子; 复合材料; 应用;
D O I
暂无
中图分类号
TQ127.11 []; TQ317 [高分子化合物产品];
学科分类号
0817 ; 0805 ; 080502 ;
摘要
石墨烯是一种单原子厚度的二维碳纳米材料,具有优异的光、电、热和力学性能,以及巨大的比表面积.石墨烯与高分子之间能够通过共价或非共价作用(氢键、π-π作用、静电作用等)进行复合.这些相互作用既增加了石墨烯在高分子中的溶解性或分散性,也可以提高复合材料的性能或拓展其功能.目前常用的制备石墨烯高分子复合材料的方法有溶液混合、熔融共混和原位聚合等.该类复合材料可以通过蒸发溶剂、溶液涂覆、真空抽滤、层层自组装等途径加工成相应的复合膜.石墨烯高分子复合薄膜在制备高强度结构材料、超级电容器、光伏器件、锂离子电池负极材料以及传感器等方面具有重要的应用价值.本文综述了近年来石墨烯高分子复合薄膜的制备和应用方面的研究进展,并对该领域进行了展望.
引用
收藏
页码:885 / 895
页数:11
相关论文
共 35 条
[21]  
High‐Nanofiller‐Content Graphene Oxide–Polymer Nanocomposites via Vacuum‐Assisted Self‐Assembly[J] . Karl W.Putz,Owen C.Compton,Marc J.Palmeri,SonBinh T.Nguyen,L. CatherineBrinson.Adv. Funct. Mater. . 2010 (19)
[22]   In-situ synthesis and characterization of electrically conductive polypyrrole/graphene nanocomposites [J].
Bose, Saswata ;
Kuila, Tapas ;
Uddin, Md Elias ;
Kim, Nam Hoon ;
Lau, Alan K. T. ;
Lee, Joong Hee .
POLYMER, 2010, 51 (25) :5921-5928
[23]   Synthesis and characterization of layer-aligned poly(vinyl alcohol)/graphene nanocomposites [J].
Yang, Xiaoming ;
Li, Liang ;
Shang, Songmin ;
Tao, Xiao-ming .
POLYMER, 2010, 51 (15) :3431-3435
[24]   Electrically conductive polyethylene terephthalate/graphene nanocomposites prepared by melt compounding [J].
Zhang, Hao-Bin ;
Zheng, Wen-Ge ;
Yan, Qing ;
Yang, Yong ;
Wang, Ji-Wen ;
Lu, Zhao-Hui ;
Ji, Guo-Ying ;
Yu, Zhong-Zhen .
POLYMER, 2010, 51 (05) :1191-1196
[25]  
Flexible conductive graphene/poly(vinyl chloride) composite thin films with high mechanical strength and thermal stability[J] . Sajini Vadukumpully,Jinu Paul,Narahari Mahanta,Suresh Valiyaveettil.Carbon . 2010 (1)
[26]  
Development of stiff, strong, yet tough composites by the addition of solvent exfoliated graphene to polyurethane[J] . Umar Khan,Peter May,Arlene O’Neill,Jonathan N. Coleman.Carbon . 2010 (14)
[27]   Fabrication of highly conducting and transparent graphene films [J].
Wang, Shu Jun ;
Geng, Yan ;
Zheng, Qingbin ;
Kim, Jang-Kyo .
CARBON, 2010, 48 (06) :1815-1823
[28]   Direct reduction of graphene oxide films into highly conductive and flexible graphene films by hydrohalic acids [J].
Pei, Songfeng ;
Zhao, Jinping ;
Du, Jinhong ;
Ren, Wencai ;
Cheng, Hui-Ming .
CARBON, 2010, 48 (15) :4466-4474
[29]   Graphene for electrochemical sensing and biosensing [J].
Pumera, Martin ;
Ambrosi, Adriano ;
Bonanni, Alessandra ;
Chng, Elaine Lay Khim ;
Poh, Hwee Ling .
TRAC-TRENDS IN ANALYTICAL CHEMISTRY, 2010, 29 (09) :954-965
[30]  
Polymer Brushes via Controlled, Surface‐Initiated Atom Transfer Radical Polymerization (ATRP) from Graphene Oxide[J] . Sun HwaLee,Daniel R.Dreyer,JinhoAn,ArunaVelamakanni,Richard D.Piner,SungjinPark,YanwuZhu,Sang OukKim,Christopher W.Bielawski,Rodney S.Ruoff.Macromol. Rapid Commun. . 2010 (3)