The effect of antimony-doping on Ge2Sb2Te5, a phase change material

被引:40
作者
Choi, Kyu-Jeong [1 ]
Yoon, Sung-Min [1 ]
Lee, Nam-Yeal [1 ]
Lee, Seung-Yun [1 ]
Park, Young-Sam [1 ]
Yu, Byoung-Gon [1 ]
Ryu, Sang-Ouk [2 ]
机构
[1] ETRI, IT Convergence & Components Lab, Taejon 305700, South Korea
[2] Dankook Univ, Dept Elect Engn, Chungnam 330714, South Korea
关键词
Phase change memory; Phase transition; Ge2Sb2Te5; excess-Sb Ge2Sb2+xTe5;
D O I
10.1016/j.tsf.2008.02.014
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The structural and electrical resistance properties of excess-Sb Ge2Sb2+xTe5 (Sb-GST) films were investigated. As the Sb-doping concentration was increased, the face center cubic structure of Sb-GST films was no longer observed, at Sb concentrations exceeding 27%, the amorphous phase directly changed to hexagonal closed-packed structures. The crystallization temperature of the 27% Sb-GST film was 15 degrees C higher than that of the Ge2Sb2Te5 (GST) film. The activation energies of the Sb-GST films also were greater than those of the GST films. These results indicate an increase in the stability of the Sb-doped films in the amorphous state compared with GST films. (c) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:8810 / 8812
页数:3
相关论文
共 14 条
[1]   Structural transformations of Ge2Sb2Te5 films studied by electrical resistance measurements [J].
Friedrich, I ;
Weidenhof, V ;
Njoroge, W ;
Franz, P ;
Wuttig, M .
JOURNAL OF APPLIED PHYSICS, 2000, 87 (09) :4130-4134
[2]  
KISSINGER HE, 1957, ANAL CHEM, V29, P1702, DOI DOI 10.1021/AC60131A045
[3]   Understanding the phase-change mechanism of rewritable optical media [J].
Kolobov, AV ;
Fons, P ;
Frenkel, AI ;
Ankudinov, AL ;
Tominaga, J ;
Uruga, T .
NATURE MATERIALS, 2004, 3 (10) :703-708
[4]  
MATSUI Y, 2006, INT EL DEV M
[5]   Single structure widely distributed in a GeTe-Sb2Te3 pseudobinary system:: A rock salt structure is retained by intrinsically containing an enormous number of vacancies within its crystal [J].
Matsunaga, T ;
Kojima, R ;
Yamada, N ;
Kifune, K ;
Kubota, Y ;
Tabata, Y ;
Takata, M .
INORGANIC CHEMISTRY, 2006, 45 (05) :2235-2241
[6]   Structural, electric and kinetic parameters of ternary alloys of GeSbTe [J].
Morales-Sánchez, E ;
Prokhorov, EF ;
González-Hernández, J ;
Mendoza-Galván, A .
THIN SOLID FILMS, 2005, 471 (1-2) :243-247
[7]  
Oh J H, 2006, INT EL DEV M, P26
[8]   Phase-change behavior of stoichiometric Ge2Sb2Te5 in phase-change random access memory [J].
Park, Jong-Bong ;
Park, Gyeong-Su ;
Baik, Hion-Suck ;
Lee, Jang-Ho ;
Jeong, Hongsik ;
Kim, Kinam .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2007, 154 (03) :H139-H141
[9]  
PELLIZZER F, 2006, S VLSI TECHN
[10]   Crystallization behavior and physical properties of Sb-excess Ge2Sb2+xTe5 thin films for phase change memory (PCM) devices [J].
Ryu, SO ;
Yoon, SM ;
Choi, KJ ;
Lee, NY ;
Park, YS ;
Lee, SY ;
Yu, BG ;
Park, JB ;
Shin, WC .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2006, 153 (03) :G234-G237