Perfluoroalkane Functionalization of NU-1000 via Solvent-Assisted Ligand Incorporation: Synthesis and CO2 Adsorption Studies

被引：478

作者：

Deria, Pravas ^{[1
,2
]}

Mondloch, Joseph E. ^{[1
,2
]}

Tylianakis, Emmanuel ^{[1
,2
,3
]}

Ghosh, Pritha ^{[1
,2
]}

Bury, Wojciech ^{[1
,2
,4
]}

Snurr, Randall Q. ^{[1
,2
]}

Hupp, Joseph T. ^{[1
,2
]}

Farha, Omar K. ^{[1
,2
]}

机构：

[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

[2] Northwestern Univ, Dept Chem & Biol Engn, Evanston, IL 60208 USA

[3] Univ Crete, Mat Sci & Technol Dept, Iraklion 71409, Crete, Greece

[4] Warsaw Univ Technol, Dept Chem, PL-00664 Warsaw, Poland

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2013年 / 135卷 / 45期

关键词：

METAL-ORGANIC FRAMEWORK; CARBON-DIOXIDE CAPTURE; POROUS MATERIALS; COORDINATION POLYMER; ENERGY-TRANSFER; SEPARATION; EXCHANGE; THERMODYNAMICS; STABILITY; CHEMISTRY;

D O I：

10.1021/ja408959g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new functionalization technique, solvent-assisted ligand incorporation (SALI), was developed to efficiently incorporate carboxylate-based functionalities in the Zr-based metal organic framework, NU-1000. Unlike previous metal node functionalization strategies, which utilize dative bonding to coordinatively unsaturated metal sites, SALT introduces functional groups as charge compensating and strongly bound moieties to the Zr-6 node. Utilizing SALT, we have efficiently attached perfluoroalkane carboxylates of various chain lengths (C-1-C-9) on the Zr-6 nodes of NU-1000. These fluoroalkane-functionalized mesoporous MOFs, termed herein SALI-n, were studied experimentally and theoretically as potential CO2 capture materials.

引用

页码：16801 / 16804

页数：4

共 54 条

[1] Stepwise Synthesis of Metal-Organic Frameworks: Replacement of Structural Organic Linkers [J].

Burnett, Brandon J. ;

Barron, Paul M. ;

Hu, Chunhua ;

Choe, Wonyoung .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (26) :9984-9987

[2] Control over Catenation in Pillared Paddlewheel Metal-Organic Framework Materials via Solvent-Assisted Linker Exchange [J].

Bury, Wojciech ;

Fairen-Jimenez, David ;

Lalonde, Marianne B. ;

Snurr, Randall Q. ;

Farha, Omar K. ;

Hupp, Joseph T. .

CHEMISTRY OF MATERIALS, 2013, 25 (05) :739-744

[3] Dramatic tuning of carbon dioxide uptake via metal substitution in a coordination polymer with cylindrical pores [J].

Caskey, Stephen R. ;

Wong-Foy, Antek G. ;

Matzger, Adam J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (33) :10870-+

[4] A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability [J].

Cavka, Jasmina Hafizovic ;

Jakobsen, Soren ;

Olsbye, Unni ;

Guillou, Nathalie ;

Lamberti, Carlo ;

Bordiga, Silvia ;

Lillerud, Karl Petter .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (42) :13850-13851

[5] Biomimetic Catalysis of a Porous Iron-Based Metal-Metalloporphyrin Framework [J].

Chen, Yao ;

Tran Hoang ;

Ma, Shengqian .

INORGANIC CHEMISTRY, 2012, 51 (23) :12600-12602

[6] Postsynthetic Methods for the Functionalization of Metal-Organic Frameworks [J].

Cohen, Seth M. .

CHEMICAL REVIEWS, 2012, 112 (02) :970-1000

[7] Understanding the Effectiveness of Fluorocarbon Ligands in Dispersing Nanoparticles in Supercritical Carbon Dioxide [J].

Dalvi, Vishwanath Haily ;

Srinivasan, Vibha ;

Rossky, Peter J. .

JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (37) :15553-15561

[8] DISPERSION POLYMERIZATIONS IN SUPERCRITICAL CARBON-DIOXIDE [J].

DESIMONE, JM ;

MAURY, EE ;

MENCELOGLU, YZ ;

MCCLAIN, JB ;

ROMACK, TJ ;

COMBES, JR .

SCIENCE, 1994, 265 (5170) :356-359

[9] Metal-Organic Framework Materials with Ultrahigh Surface Areas: Is the Sky the Limit? [J].

Farha, Omar K. ;

Eryazici, Ibrahim ;

Jeong, Nak Cheon ;

Hauser, Brad G. ;

Wilmer, Christopher E. ;

Sarjeant, Amy A. ;

Snurr, Randall Q. ;

Nguyen, SonBinh T. ;

Yazaydin, A. Oezguer ;

Hupp, Joseph T. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (36) :15016-15021

[10]

Farha OK, 2010, NAT CHEM, V2, P944, DOI [10.1038/NCHEM.834, 10.1038/nchem.834]

← 1 2 3 4 5 6 →