Stepwise Synthesis of Metal-Organic Frameworks: Replacement of Structural Organic Linkers

被引：293

作者：

Burnett, Brandon J. ^{[1
]}

Barron, Paul M. ^{[1
]}

Hu, Chunhua ^{[3
]}

Choe, Wonyoung ^{[1
,2
]}

机构：

[1] Univ Nebraska, Dept Chem, Lincoln, NE 68588 USA

[2] Univ Nebraska, Nebraska Ctr Mat & Nanosci, Lincoln, NE 68588 USA

[3] NYU, Dept Chem, New York, NY 10003 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 26期

关键词：

PORE-SIZE; DESIGN; EXCHANGE; SERIES; FUNCTIONALITY; ISOMERISM; STORAGE; MOFS;

D O I：

10.1021/ja201911v

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We demonstrate how a single-crystal to single-crystal transformation resulting from bridging-linker replacement is possible in extended 2D and 3D metal organic frameworks (MOFs) by introducing pillared paddle-wheel MOF structures into a solution containing dipyridyl linkers. No lateral movement of the layers was observed during this transformation, creating a templating effect from the "parent" structure to the "daughter" structure. A previously unattainable structure was obtained by a two-step synthetic method utilizing the bridging-linker replacement transformation method. Additionally, a bridging-linker insertion was observed when excess linker was used with the 2D MOF structure, inducing an overall 2D to 3D transformation.

引用

收藏

页码：9984 / 9987

页数：4

相关论文

共 44 条

[1] Crystal porosity and the burden of proof [J].

Barbour, LJ .

CHEMICAL COMMUNICATIONS, 2006, (11) :1163-1168

[2] Reversible Two-Dimensional-Three Dimensional Framework Transformation within a Prototype Metal-Organic Framework [J].

Chen, Zhenxia ;

Xiang, Shengchang ;

Zhao, Dongyuan ;

Chen, Banglin .

CRYSTAL GROWTH & DESIGN, 2009, 9 (12) :5293-5296

[3] Highly tunable metal-organic frameworks with open metal centers [J].

Choi, Eun-Young ;

Wray, Curtis A. ;

Hu, Chunhua ;

Choe, Wonyoung .

CRYSTENGCOMM, 2009, 11 (04) :553-555

[4] Pillared Porphyrin Homologous Series: Intergrowth in Metal-Organic Frameworks [J].

Choi, Eun-Young ;

Barron, Paul M. ;

Novotny, Richard W. ;

Son, Hyun-Tak ;

Hu, Chunhua ;

Choe, Wonyoung .

INORGANIC CHEMISTRY, 2009, 48 (02) :426-428

[5] Dynamic and redox active pillared bilayer open framework: Single-crystal-to-single-crystal transformations upon guest removal, guest exchange, and framework oxidation [J].

Choi, HJ ;

Suh, MP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (48) :15844-15851

[6] Structural Variation in Porphyrin Pillared Homologous Series: Influence of Distinct Coordination Centers for Pillars on Framework Topology [J].

Chung, Haemi ;

Barron, Paul M. ;

Novotny, Richard W. ;

Son, Hyun-Tak ;

Hu, Chunhua ;

Choe, Wonyoung .

CRYSTAL GROWTH & DESIGN, 2009, 9 (07) :3327-3332

[7] Modifying MOFs: new chemistry, new materials [J].

Cohen, Seth M. .

CHEMICAL SCIENCE, 2010, 1 (01) :32-36

[8] Hydrogen storage in metal-organic frameworks [J].

Collins, David J. ;

Zhou, Hong-Cai .

JOURNAL OF MATERIALS CHEMISTRY, 2007, 17 (30) :3154-3160

[9] Metathesis in Single Crystal: Complete and Reversible Exchange of Metal Ions Constituting the Frameworks of Metal-Organic Frameworks [J].

Das, Sunirban ;

Kim, Hyunuk ;

Kim, Kimoon .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (11) :3814-+

[10] Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage [J].

Eddaoudi, M ;

Kim, J ;

Rosi, N ;

Vodak, D ;

Wachter, J ;

O'Keeffe, M ;

Yaghi, OM .

SCIENCE, 2002, 295 (5554) :469-472

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