Pillared Porphyrin Homologous Series: Intergrowth in Metal-Organic Frameworks

被引：167

作者：

Choi, Eun-Young ^{[1
]}

Barron, Paul M. ^{[1
]}

Novotny, Richard W. ^{[1
]}

Son, Hyun-Tak ^{[1
]}

Hu, Chunhua ^{[2
]}

Choe, Wonyoung ^{[1
]}

机构：

[1] Univ Nebraska, Dept Chem, Lincoln, NE 68588 USA

[2] NYU, Dept Chem, New York, NY 10003 USA

来源：

INORGANIC CHEMISTRY | 2009年 / 48卷 / 02期

关键词：

MICROPOROUS COORDINATION POLYMERS; SECONDARY-BUILDING UNITS; PADDLE-WHEEL; SELECTIVE SORPTION; HYDROGEN STORAGE; GAS-ADSORPTION; CRYSTAL-STRUCTURE; DESIGN; NETS; MOTIFS;

D O I：

10.1021/ic801677y

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We report three new porphyrin-based, pillared paddle-wheel homologous series: porphyrin paddle-wheel frameworks PPF-3, -4, and -5. These compounds are assembled from free base or palladium tetrakis(4-carboxyphenyl)porphine, M(NO3)(2) (M = Co and Zn), and 4,4'-bipyridine via solvothermal reactions. The resulting solids exhibit 3D metal-organic frameworks, where 2D layers are pillared by bipyridine with three different packing arrangements.

引用

页码：426 / 428

页数：3

共 45 条

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