Reversible Two-Dimensional-Three Dimensional Framework Transformation within a Prototype Metal-Organic Framework

被引：90

作者：

Chen, Zhenxia ^{[1
,2
]}

Xiang, Shengchang ^{[1
]}

Zhao, Dongyuan ^{[2
]}

Chen, Banglin ^{[1
]}

机构：

[1] Univ Texas San Antonio, Dept Chem, San Antonio, TX 78249 USA

[2] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China

来源：

CRYSTAL GROWTH & DESIGN | 2009年 / 9卷 / 12期

关键词：

SINGLE-CRYSTAL TRANSFORMATION; GAS SORPTION PROPERTIES; COORDINATION POLYMERS; MICROPOROUS METAL; DESIGN; FLEXIBILITY; ADSORPTION; NETWORK; CONNECTIVITY; SEPARATION;

D O I：

10.1021/cg900797y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The prototype three-dimensional metal-organic framework Zn-2(BDC)(2)(Dabco)center dot 4DMF center dot 0.5H(2)O(MOF-1) and two-dimensional Zn-2(BDC)(2)(H2O)(2)center dot(DMF) (MOF-2) can be reversibly transformed with each other in which the activated MOF-2 exhibits high selective gas adsorption with respect to C2H2/CO2 at room temperature.

引用

页码：5293 / 5296

页数：4

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