Biomimetic Catalysis of a Porous Iron-Based Metal-Metalloporphyrin Framework

被引：226

作者：

Chen, Yao ^{[1
]}

Tran Hoang ^{[1
]}

Ma, Shengqian ^{[1
]}

机构：

[1] Univ S Florida, Dept Chem, Tampa, FL 33620 USA

来源：

INORGANIC CHEMISTRY | 2012年 / 51卷 / 23期

关键词：

ORGANIC FRAMEWORKS; PORPHYRIN; ADSORPTION; MYOGLOBIN; CAPTURE; CAGES; MOF;

D O I：

10.1021/ic301923x

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A porous metal-metalloporphyrin framework, MMPF-6, based upon an iron(III)-metalated porphyrin ligand and a secondary binding unit of a zirconium oxide cluster was constructed; MMPF-6 demonstrated interesting peroxidase activity comparable to that of the heme protein myoglobin as well as exhibited solvent adaptability of retaining the peroxidase activity in an organic solvent.

引用

收藏

页码：12600 / 12602

页数：3

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