B-octamethyl-[12]mercuracarborand-4 as host for "naked" fluoride ions

被引：38

作者：

Bayer, MJ ^{[1
]}

Jalisatgi, SS ^{[1
]}

Smart, B ^{[1
]}

Herzog, A ^{[1
]}

Knobler, CB ^{[1
]}

Hawthorne, MF ^{[1
]}

机构：

[1] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 14期

关键词：

carboranes; fluoride; host-guest systems; Lewis acids; mercury;

D O I：

10.1002/anie.200352899

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Fs in rings: A cyclic multidentate Lewis acidic receptor is coordinated by a weakly bonded fluoride ion in 1 (see picture). This host-guest system has properties such as air- and moisture-stability, solubility in common organic solvents, and utility as a source for naked" fluoride ions generated in situ."

引用

页码：1854 / 1857

页数：4

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