α-siloxyamides from a carbamoylsilane and carbonyl compounds

被引：26

作者：

Cunico, RF ^{[1
]}

机构：

[1] No Illinois Univ, Dept Chem & Biochem, De Kalb, IL 60115 USA

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 03期

关键词：

alpha-siloxyamide; alpha-hydroxyamide; carbamoylsilane;

D O I：

10.1016/S0040-4039(01)02177-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of a carbamoylsilane with aldehydes or ketones affords alpha-siloxyamides. The addition reaction is catalyzed by fluoride ion (TBAT, 25-50degreesC), but proceeds in the absence of catalyst at higher temperatures (50-100degreesC). (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：355 / 358

页数：4

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