Au32:: A 24-carat golden fullerene

被引:281
作者
Johansson, MP
Sundholm, D
Vaara, J
机构
[1] Univ Helsinki, Dept Chem, Lab Instruct Swedish, FIN-00014 Helsinki, Finland
[2] Univ Helsinki, Dept Chem, Chem Phys Lab, FIN-00014 Helsinki, Finland
关键词
D O I
10.1002/anie.200453986
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Golden balls! Relativistic quantum chemical theory suggests the existence of an interesting and surprising gold cluster. The all-gold fullerene Au 32 (see picture) is structurally very similar to the familiar buckminsterfullerene C60, as it is approximately the same size and hollow. Au32 is stabilized by relativistic effects and spherical aromaticity; the magnetic shielding at the center of the fullerene has the highest predicted value.
引用
收藏
页码:2678 / 2681
页数:4
相关论文
共 49 条
  • [21] Synthesis and characterization of helical multi-shell gold nanowires
    Kondo, Y
    Takayanagi, K
    [J]. SCIENCE, 2000, 289 (5479) : 606 - 608
  • [22] C-60 - BUCKMINSTERFULLERENE
    KROTO, HW
    HEATH, JR
    OBRIEN, SC
    CURL, RF
    SMALLEY, RE
    [J]. NATURE, 1985, 318 (6042) : 162 - 163
  • [23] Kutzelnigg W., 1991, NMR, V213, P165, DOI DOI 10.1007/978-3-642-75932-1_3
  • [24] A GRAPHICS PROGRAM FOR THE ANALYSIS AND DISPLAY OF MOLECULAR-DYNAMICS TRAJECTORIES
    LAAKSONEN, L
    [J]. JOURNAL OF MOLECULAR GRAPHICS, 1992, 10 (01): : 33 - &
  • [25] Au20:: A tetrahedral cluster
    Li, J
    Li, X
    Zhai, HJ
    Wang, LS
    [J]. SCIENCE, 2003, 299 (5608) : 864 - 867
  • [26] Experimental observation and confirmation of icosahedral W@Au12 and Mo@Au12 molecules
    Li, X
    Kiran, B
    Li, J
    Zhai, HJ
    Wang, LS
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2002, 41 (24) : 4786 - 4789
  • [27] LI X, 2002, ANGEW CHEM, V114, P4980
  • [28] The emerging field of nanotube biotechnology
    Martin, CR
    Kohli, P
    [J]. NATURE REVIEWS DRUG DISCOVERY, 2003, 2 (01) : 29 - 37
  • [29] Perdew JP, 1997, PHYS REV LETT, V78, P1396, DOI 10.1103/PhysRevLett.77.3865
  • [30] Pyykkö P, 2002, ANGEW CHEM INT EDIT, V41, P2174, DOI 10.1002/1521-3773(20020617)41:12<2174::AID-ANIE2174>3.0.CO