Synthesis and characterization of 'calixsalens': a new class of macrocyclic chiral ligands

被引：57

作者：

Li, ZM ^{[1
]}

Jablonski, C ^{[1
]}

机构：

[1] Mem Univ Newfoundland, Dept Chem, St Johns, NF A1B 3X7, Canada

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 16期

关键词：

D O I：

10.1039/a900018f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Template directed reaction of dialdehydes and (R,R)- or (S,S)-1,2-diaminocyclohexane affords a practical route to chiral, metal-free macrocyclic salen dimers which have a novel calixarene-like structure and show catalytic activity for enantioselective epoxidation of unfunctionalized alkenes in the presence of Mn-III-NaOCl (aq.).

引用

页码：1531 / 1532

页数：2

共 31 条

[1]

BERNARDO KDS, 1995, NEW J CHEM, V19, P129

[2] DIALDEHYDE PLUS DIAMINE - POLYMER OR MACROCYCLE [J].

BRUNNER, H ;

SCHIESSLING, H .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1994, 33 (01) :125-126

[3] SELECTIVE REACTIONS USING METAL PHENOXIDES .1. REACTIONS WITH FORMALDEHYDE [J].

CASIRAGHI, G ;

CASNATI, G ;

CORNIA, M ;

POCHINI, A ;

PUGLIA, G ;

SARTORI, G ;

UNGARO, R .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1978, (04) :318-321

[4] REGIOSELECTIVE AND ENANTIOSELECTIVE EPOXIDATION CATALYZED BY METALLOPORPHYRINS [J].

COLLMAN, JP ;

ZHANG, XM ;

LEE, VJ ;

UFFELMAN, ES ;

BRAUMAN, JI .

SCIENCE, 1993, 261 (5127) :1404-1411

[5] THE DESIGN OF MOLECULAR HOSTS, GUESTS, AND THEIR COMPLEXES (NOBEL LECTURE) [J].

CRAM, DJ .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (08) :1009-1020

[6]

De BB, 1997, J POLYM SCI POL CHEM, V35, P1809

[7] A new palladium(II)-catalyzed asymmetric chlorohydrin synthesis [J].

El-Qisairi, A ;

Hamed, O ;

Henry, PM .

JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (09) :2790-2791

[8] Aerobic catalytic epoxidation of unfunctionalized olefins using a new (salen) manganese(III) complex bearing a sesquiterpene Salicylaldehyde derivative [J].

Fernandez, I ;

Pedro, JR ;

delaSalud, R .

TETRAHEDRON, 1996, 52 (36) :12031-12038

[9] BIMETALLIC REACTIVITY - CONTROLLED SYNTHESIS OF MONOMETALLIC AND HOMO-BIMETALLIC AND HETEROBIMETALLIC COMPLEXES OF A CHIRAL BINUCLEATING MACROCYCLIC LIGAND BEARING 6- AND 4-COORDINATE SITES [J].

FRASER, C ;

OSTRANDER, R ;

RHEINGOLD, AL ;

WHITE, C ;

BOSNICH, B .

INORGANIC CHEMISTRY, 1994, 33 (02) :324-337

[10] BIMETALLIC REACTIVITY - INVESTIGATION OF METAL-METAL INTERACTION IN COMPLEXES OF A CHIRAL MACROCYCLIC BINUCLEATING LIGAND BEARING 6-COORDINATE AND 4-COORDINATE SITES [J].

FRASER, C ;

BOSNICH, B .

INORGANIC CHEMISTRY, 1994, 33 (02) :338-346

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