The importance of the linking bridge in donor-C60 electroactive dyads

被引:20
作者
Langa, F [1 ]
de la Cruz, P
Delgado, JL
Gómez-Escalonilla, MJ
González-Cortés, A
de la Hoz, A
López-Arza, V
机构
[1] Univ Castilla La Mancha, Fac Ciencias Medio Ambiente, Toledo 45071, Spain
[2] Univ Complutense, Fac Quim, E-28040 Madrid, Spain
[3] Univ Castilla La Mancha, Fac Ciencias Quim, Ciudad Real 45071, Spain
[4] Univ Castilla La Mancha, Escuela Ingn Tecn Ind, Ciudad Real 45071, Spain
关键词
D O I
10.1039/b106012k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The synthesis, spectroscopic characterization, electrochemistry and photophysical measurements of three 2-methoxyphenylfullerene derivatives are described and their properties compared. Cyclic and Osteryoung square-wave voltammetry studies indicate that the pyrazolino [60] fullerene shows improved electron affinity in comparison to the parent C-60. Preliminary photophysical studies suggest the occurrence of an electron transfer process.
引用
收藏
页码:76 / 80
页数:5
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