Combining transition metal catalysis and organocatalysis - an update

被引:593
作者
Du, Zhenting [1 ]
Shao, Zhihui [1 ,2 ]
机构
[1] NW A&F Univ, Coll Sci, Yangling 712100, Shaanxi, Peoples R China
[2] Yunnan Univ, Key Lab Med Chem Nat Resource, Minist Educ, Sch Chem Sci & Technol, Kunming 650091, Yunnan, Peoples R China
关键词
LEWIS-BASE CATALYSIS; ENANTIOSELECTIVE ALPHA-TRIFLUOROMETHYLATION; CHIRAL BRONSTED ACID-RH-2(OAC)(4); ACID COOPERATIVE CATALYSIS; N-HETEROCYCLIC CARBENE; DIELS-ALDER REACTION; RELAY CATALYSIS; MERGING ORGANOCATALYSIS; ALLYLIC ALKYLATION; DUAL CATALYSIS;
D O I
10.1039/c2cs35258c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The combination of transition metal catalysis and organocatalysis as a new and exciting research area has attracted increasing attention as it can enable the development of unprecedented transformations that is not possible by use of either of the catalytic systems alone, and can improve the reactivity, efficiency and stereocontrol of existing chemical transformations. In this review, we summarize recent remarkable progress in the field of combined transition metal catalysis and organocatalysis, further highlighting the potential of this new and exciting research area and the many challenges that still remain for the future.
引用
收藏
页码:1337 / 1378
页数:42
相关论文
共 170 条
[1]   Direct Regiospecific and Highly Enantioselective Intermolecular a-Allylic Alkylation of Aldehydes by a Combination of Transition-Metal and Chiral Amine Catalysts [J].
Afewerki, Samson ;
Ibrahem, Ismail ;
Rydfjord, Jonas ;
Breistein, Palle ;
Cordova, Armando .
CHEMISTRY-A EUROPEAN JOURNAL, 2012, 18 (10) :2972-2977
[2]   Catalytic Enantioselective β-Alkylation of α,β-Unsaturated Aldehydes by Combination of Transition-Metal- and Aminocatalysis: Total Synthesis of Bisabolane Sesquiterpenes [J].
Afewerki, Samson ;
Breistein, Palle ;
Pirttila, Kristian ;
Deiana, Luca ;
Dziedzic, Pawel ;
Ibrahem, Ismail ;
Cordova, Armando .
CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (32) :8784-8788
[3]   One-pot sequential alcohol oxidation and asymmetric α-oxyamination in aqueous media using recyclable resin-supported peptide catalyst [J].
Akagawa, Kengo ;
Fujiwara, Takuma ;
Sakamoto, Seiji ;
Kudo, Kazuaki .
CHEMICAL COMMUNICATIONS, 2010, 46 (42) :8040-8042
[4]   Efficient Asymmetric α-Oxyamination of Aldehydes by Resin-Supported Peptide Catalyst in Aqueous Media [J].
Akagawa, Kengo ;
Fujiwara, Takuma ;
Sakamoto, Seiji ;
Kudo, Kazuaki .
ORGANIC LETTERS, 2010, 12 (08) :1804-1807
[5]   Enantioselective Mannich-type reaction catalyzed by a chiral Bronsted acid [J].
Akiyama, T ;
Itoh, J ;
Yokota, K ;
Fuchibe, K .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (12) :1566-1568
[6]   Stronger bronsted acids [J].
Akiyama, Takahiko .
CHEMICAL REVIEWS, 2007, 107 (12) :5744-5758
[7]   Organocatalytic Domino Reactions [J].
Alba, Andrea-Nekane ;
Companyo, Xavier ;
Viciano, Monica ;
Rios, Ramon .
CURRENT ORGANIC CHEMISTRY, 2009, 13 (14) :1432-1474
[8]   Tandem Cyclization-Michael Reaction by Combination of Metal- and Organocatalysis [J].
Aleman, Jose ;
del Solar, Virginia ;
Martin-Santos, Cecilia ;
Cubo, Leticia ;
Navarro Ranningers, Carmen .
JOURNAL OF ORGANIC CHEMISTRY, 2011, 76 (17) :7287-7293
[9]   Enantioselective α-Arylation of Aldehydes via the Productive Merger of lodonium Salts and Organocatalysis [J].
Allen, Anna E. ;
MacMillan, David W. C. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (12) :4260-4263
[10]   The Productive Merger of Iodonium Salts and Organocatalysis: A Non-photolytic Approach to the Enantioselective α-Trifluoromethylation of Aldehydes [J].
Allen, Anna E. ;
MacMillan, David W. C. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (14) :4986-+