Combining transition metal catalysis and organocatalysis - an update

被引:593
作者
Du, Zhenting [1 ]
Shao, Zhihui [1 ,2 ]
机构
[1] NW A&F Univ, Coll Sci, Yangling 712100, Shaanxi, Peoples R China
[2] Yunnan Univ, Key Lab Med Chem Nat Resource, Minist Educ, Sch Chem Sci & Technol, Kunming 650091, Yunnan, Peoples R China
关键词
LEWIS-BASE CATALYSIS; ENANTIOSELECTIVE ALPHA-TRIFLUOROMETHYLATION; CHIRAL BRONSTED ACID-RH-2(OAC)(4); ACID COOPERATIVE CATALYSIS; N-HETEROCYCLIC CARBENE; DIELS-ALDER REACTION; RELAY CATALYSIS; MERGING ORGANOCATALYSIS; ALLYLIC ALKYLATION; DUAL CATALYSIS;
D O I
10.1039/c2cs35258c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The combination of transition metal catalysis and organocatalysis as a new and exciting research area has attracted increasing attention as it can enable the development of unprecedented transformations that is not possible by use of either of the catalytic systems alone, and can improve the reactivity, efficiency and stereocontrol of existing chemical transformations. In this review, we summarize recent remarkable progress in the field of combined transition metal catalysis and organocatalysis, further highlighting the potential of this new and exciting research area and the many challenges that still remain for the future.
引用
收藏
页码:1337 / 1378
页数:42
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