Nitrogen-Doped Carbon Nanocages as Efficient Metal-Free Electrocatalysts for Oxygen Reduction Reaction

被引：719

作者：

Chen, Sheng ^{[1
,2
]}

Bi, Jiyu ^{[1
,2
]}

Zhao, Yu ^{[1
,2
]}

Yang, Lijun ^{[1
,2
]}

Zhang, Chen ^{[1
,2
]}

Ma, Yanwen ^{[3
]}

Wu, Qiang ^{[1
,2
]}

Wang, Xizhang ^{[1
,2
]}

Hu, Zheng ^{[1
,2
]}

机构：

[1] Nanjing Univ, Key Lab Mesoscop Chem MOE, Sch Chem & Chem Engn, Nanjing 210093, Jiangsu, Peoples R China

[2] Nanjing Univ, Jiangsu Prov Lab Nanotechnol, Sch Chem & Chem Engn, Nanjing 210093, Jiangsu, Peoples R China

[3] Nanjing Univ Posts & Telecommun, Jiangsu Key Lab Organ Elect & Informat Displays, Inst Adv Mat, Nanjing 210046, Jiangsu, Peoples R China

来源：

ADVANCED MATERIALS | 2012年 / 24卷 / 41期

关键词：

metal-free electrocatalysts; oxygen reduction reaction; nitrogen-doped carbon nanocages; high specific surface area; fuel cells; FUEL-CELL; NANOTUBES; CATALYST; ELECTRODE; GRAPHENE; BORON;

D O I：

10.1002/adma.201202424

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal-free ORR Electrocatalysts: N-doped carbon nanocages (NCNCs) with large specific surface areas of up to 1393 m(2) g(-1), which demonstrate excellent ORR performance with high activity, are produced for the first time. Without the interference of any ORR-active metal impurities in NCNCs, the experimental results confirm that the ORR activity originates from the N-doped carbon species.

引用

页码：5593 / 5597

页数：5

共 28 条

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