Catalytic Solvolytic and Hydrolytic Degradation of Toxic Methyl Paraoxon with La(catecholate)-Functionalized Porous Organic Polymers

被引：81

作者：

Totten, Ryan K.

Weston, Mitchell H.

Park, Jin Kuen

Farha, Omar K. ^{[1
]}

Hupp, Joseph T.

Nguyen, SonBinh T.

机构：

[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

来源：

ACS CATALYSIS | 2013年 / 3卷 / 07期

关键词：

porous organic polymers; catechol; catalysis; organophosphates; lanthanum; FOLD ACCELERATION; GAS-STORAGE; METHANOLYSIS; DECOMPOSITION; DESTRUCTION; FRAMEWORK; TRIESTER; ROBUST; AGENTS;

D O I：

10.1021/cs4001738

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Two robust catechol-functionalized porous organic polymers (catPOPs) with different T-d-directing nodes were synthesized using a cobalt-catalyzed acetylene trimetization (CCAT) strategy. Postsynthesis metallation was readily carried out with La(acac)(3) to afford catalytically active La-functionalized catPOPs for the solvolytic and hydrolytic degradation of the toxic organophosphate compound methyl paraoxon, a simulant for nerve agents.

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页码：1454 / 1459

页数：6

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