Metal-Organic Conjugated Microporous Polymers

被引:316
作者
Jiang, Jia-Xing [1 ,2 ]
Wang, Chao [1 ,2 ]
Laybourn, Andrea [1 ,2 ]
Hasell, Tom [1 ,2 ]
Clowes, Rob [1 ,2 ]
Khimyak, Yaroslav Z. [1 ,2 ]
Xiao, Jianliang [1 ,2 ]
Higgins, Simon J. [1 ,2 ]
Adams, Dave J. [1 ,2 ]
Cooper, Andrew I. [1 ,2 ]
机构
[1] Univ Liverpool, Dept Chem, Liverpool, Merseyside, England
[2] Univ Liverpool, Ctr Mat Discovery, Liverpool, Merseyside, England
基金
英国工程与自然科学研究理事会;
关键词
conjugated microporous polymers; coordination polymers; polymerization; porous materials; HIGH-SURFACE-AREA; HYDROGEN STORAGE MATERIALS; INTRINSIC MICROPOROSITY; HETEROGENEOUS CATALYSIS; NETWORKS; FRAMEWORKS; POLYMERIZATION; ADSORPTION; CHEMISTRY; MONOMERS;
D O I
10.1002/anie.201005864
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Two versatile strategies for preparing metal-organic conjugated microporous polymers (MO-CMPs) containing metals such as rhenium, rhodium, and iridium are described (see example). These materials combine the uninterrupted extended electronic conjugation in the network with catalytically active metal sites. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:1072 / 1075
页数:4
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