Palladium-Catalyzed Acylation of sp2 C-H bond: Direct Access to Ketones from Aldehydes

被引：268

作者：

Jia, Xiaofei ^{[1
]}

Zhang, Shouhui ^{[1
]}

Wang, Wenhui ^{[1
]}

Luo, Fang ^{[1
]}

Cheng, Jiang ^{[1
,2
]}

机构：

[1] Wenzhou Univ, Coll Chem & Mat Engn, Wenzhou 325027, Peoples R China

[2] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

来源：

ORGANIC LETTERS | 2009年 / 11卷 / 14期

基金：

芬兰科学院;

关键词：

DIRECT ORTHO ARYLATION; DIRECT FUNCTIONALIZATION; COUPLING REACTION; AROMATIC IMINES; ARYL BROMIDES; ACTIVATION; CARBON; HETEROCYCLES; ACIDS; PD;

D O I：

10.1021/ol900934g

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A palladium-catalyzed direct access to ketones from aldehydes via C-H cleavage of arenes is described. The procedure utilizes air as a clean and free terminal oxidant.

引用

页码：3120 / 3123

页数：4

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