Recent applications of olefin metathesis and related reactions in carbohydrate chemistry

被引:220
作者
Roy, R [1 ]
Das, SK [1 ]
机构
[1] Univ Ottawa, Dept Chem, Ottawa, ON K1N 6N5, Canada
关键词
D O I
10.1039/a907712j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The potential use of olefin metathesis reactions in carbohydrate chemistry is discussed. In recent years, the use of olefin metathesis reactions for the construction of carbon--carbon bonds has significantly expanded with the development of efficient and well-defined catalytic systems (1-7). These catalytic systems have found extensive use through cross-metathesis, ring-closing metathesis and ring-opening metathesis reactions for the syntheses of many carbohydrate-containing natural products. In some cases it has been shown that carbohydrate molecules can be synthesized from non-carbohydrate precursors using this simple but efficient procedure.
引用
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页码:519 / 529
页数:11
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